Publication
697
Dalton Trans., 41, 1675-1677, 2012
DOI: 10.1039/C1DT11858G
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Influence of second sphere hydrogen bonding interaction on a manganese(II)-aquo complex |
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Sanae El Ghachtouli, Régis Guillot, Pierre Dorlet, Elodie Anxolabéhère-Mallart and Ally Aukauloo
Institut de Chimie Moléculaire et des Matériaux d'Orsay, UMR-CNRS 8182, Université de Paris-Sud XI, F-91405, Orsay, France
Laboratoire Stress Oxydant et Detoxication, CNRS URA 2096 and CEA/iBiTec-S/SB2SM, CEA Saclay, 91191 Gif-sur-Yvette Cedex, France
Laboratoire d’Electrochimie Moléculaire, UMR 7591 CNRS, Université Paris Diderot, Sorbonne Paris Cité, 15 rue Jean-Antoine de Baïf, F-75205 Paris Cedex 13, France
CEA, iBiTec-S, Service de Bioénergétique Biologie Structurale et Mécanismes (SB2SM), F-91191, Gif-sur-Yvette, FranceCEA, iBiTec-S, SB2SM, F-91191, Gif-sur-Yvette, France
We have developed a pentadentate N4O ligand scaffold with a benzimidazole group placed in a rigid fashion to develop hydrogen bonding interaction with the ligand in the sixth position. The mononuclear Mn(II) complex with a water molecule was isolated and characterized. We discuss the role of the outer sphere ligand in stabilising a Mn(II)-aquo complex. |