Publication
725
Chem. Commun., 49 (17), 5696-5698, 2013
DOI: 10.1039/C3CC41300D
|
PDF |
|
|
|
|
|
Electrochemical formation of MnIII-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands |
|
|
|
Sanae El Ghachtouli, Vincent Ching, Benedikt Lassalle-Kaiser, Régis Guillot,Domenick F. Leto, Swarup Chattopadhyay, Timothy A. Jackson, Pierre Dorlet and Elodie Anxolabéhère-Mallart
- ICMMO, CNRS UMR 8182, Univ Paris-Sud, Bât. 420, 15 rue Georges Clemenceau, 91405 Orsay Cedex, France
-
Laboratoire d'Electrochimie Moléculaire, UMR CNRS 7591, Univ Paris Diderot, Sorbonne Paris Cité, Bâtiment Lavoisier, 15 rue Jean-Antoine de Baïf, 75205 Paris Cedex 13, France
- Laboratoire des BioMolécules, UMR CNRS 7203 Université Pierre et Marie Curie, Ecole Normale Supérieure, Département de Chimie, 24, rue Lhomond, 75005 Paris, France
- Department of Chemistry and Center for Environmentally Beneficial Catalysis, University of Kansas, Lawrence, Kansas 66045, USA
- CNRS, UMR 8221, Laboratoire Stress Oxydant et Détoxication, CEA Saclay, 91191 Gif-sur-Yvette Cedex, France
A novel and efficient method for preparing [MnIII(O2)(L)]+ complexes using electrochemically generated superoxide is reported, with the reaction probed by low temperature electronic absorption and electron paramagnetic resonance spectroscopic techniques. |