Publication
760
Chem. Commun., 50, 14616-14619, 2014
DOI:10.1039/C4CC04134H
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Electrochemical controlling and monitoring of halogen bond formation in solution |
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Sihem Groni, Tanguy Maby-Raud, Claire Fave, Mathieu Branca, and Bernd Schöllhorn
Laboratoire d'Electrochimie Moléculaire, UMR CNRS 7591, Université Paris Diderot, Sorbonne Paris Cité, 15 rue Jean-Antoine de Baïf, 75205 Paris cedex, France
Cyclic voltammetry has been used for the first time to probe and to control the formation of non-covalent halogen bonding (XB) via redox switching. These results strongly encourage the use of electrochemistry as an economical and precisely controllable tool for the investigation of XB in solution. |