Publication
761
CrystEngComm, 16, 10380-10384, 2014
DOI:10.1039/C4CE01704H
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Directed synthesis of a halogen-bonded open porphyrin network |
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Jean-Laurent Syssa-Magale, Kamal Boubekeur, Jacques Leroy, Lise-Marie Chamoreau, Claire Fave, and Bernd Schöllhorn
Ecole Normale Supérieure, Département de Chimie, UMR 8640 CNRS “PASTEUR”, 24 rue Lhomond, 75005 Paris, France
Institut Parisien de Chimie Moleculaire – UMR CNRS 8232 UPMC Université Paris 6, 4 place Jussieu, 75252 Paris Cedex 5, France
Laboratoire d'Electrochimie Moléculaire, UMR CNRS 7591, Université Paris Diderot, Sorbonne Paris Cité, 15 rue Jean-Antoine de Baïf, 75205 Paris cedex, France
A strategy for the elaboration of a halogen-bonded porphyrin network is reported. The progressive introduction of geometric constraints via the modulation of building blocks and self-assembly via strong and directional halogen bonding led successfully to the construction of an open porphyrin network with nano-sized tubular channels. |
