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Laboratoire d'Electrochimie Moleculaire, LEM, Paris

UMR CNRS - Université Paris Diderot - Paris France

Master Frontiers in Chemistry | UFR de Chimie - Université Paris Diderot - Paris 7 CNRS - Institut de chimie Université de Paris Master Chimie Sorbonne Paris Cité UFR de Chimie - Université Paris Diderot - Paris 7 CNRS - Institut de chimie
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Université Paris Diderot
Université de Paris CNRS, Centre National de la Recherche Scientifique

Le LEM - Publications: Abstracts

Publication 849

Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, Elsevier , 2017


Electrochemical Activation of Molecular Catalysts: From Basics to Applications


Laure Fillaud, Emmanuel Maisonhaute, Claire Fave and Marc Robert

Sorbonne Universités, Laboratoire Interfaces et Systèmes Electrochimiques, Paris, France
Laboratoire d'Electrochimie Moléculaire, Université Paris Diderot, Sorbonne Paris Cité, Bâtiment Lavoisier, Paris, France

In this article, the fundamental concepts of redox catalysis are first presented. While the one electron scheme provides general guidelines, it needs to be adapted when more complex systems involving several chemical reactions and electron transfer are concerned. Secondly, the structure of some bioinspired or biomimetic molecular catalysts for oxygen and proton reduction reactions is described. In that later case, a key aspect is to prevent degradation of the catalyst while keeping important turnover frequency, but also to keep the activity upon electrode functionalization.

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