Publication
907
Chem. Commun., 56, 7491-7494, 2020
DOI:10.1039/D0CC02604B
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Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine–dioxime catalysts under both aqueous and organic conditions |
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Chun-Leung Kwok, Shun-Cheung Cheng, Pui-Yu Ho, Shek-Man Yiu, Wai-Lun Man, Vonika Ka-Man Au, Po-Keung Tsang, Chi-Fai Leung, Chi-Chiu Ko, and Marc Robert
Department of Science and Environmental Studies, The Education University of Hong Kong, 10 Lo Ping Road, Tai Po, New Territories, Hong Kong, China
Department of Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, China
Department of Chemistry, Hong Kong Baptist University, Waterloo Road, Kowloon, Hong Kong
Université de Paris, Laboratoire d’Electrochimie Moléculaire, CNRS, F-75013 Paris, France
Institut Universitaire de France (IUF), F-75005 Paris, France
The photocatalytic generation of an NADH synthetic analogue, i.e. 1-benzyl-1,4-dihydronicotinamide (1,4-BNAH), has been studied using the cobalt diimino-dioxime complexes and the BF2-bridged derivative as catalysts. 1,4-BNAH was produced in both aqueous and organic media at unprecedented turnover numbers with metal and organic photosensitizers, respectively. |
