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Laboratoire d'Electrochimie Moleculaire, LEM, Paris

UMR CNRS - Université de Paris - Paris France

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Research Group "ELIAS"

" Electrochemistry and Engineering of Supramolecular Assemblies "

     
       

 

Home> Research Groups > LEM "ELIAS"


The team is particularly interested in the development and study of different supramolecular assemblies by electrochemical methods, whether in homogeneous solution or immobilized on the electrode surface. The design, synthesis and assembly of molecules with multiple chemical and physico-chemical properties and depending on purpose the functionalization of electrodes by immobilization of these molecules allows the development of electrochemical devices for analytical applications and fundamental research. We study non-covalent interactions between small molecules but also more complex systems such as interactions with bio-macromolecules. Molecular engineering and molecular electrochemistry are the team's main tools.



Topics

1- Surface functionalization – electro-assisted formation of redox-active self-assembled monolayers

2- Electrochemical activation and detection of Halogen bond in solution and on surface

3- Ultrasensitive detection of target nucleic acids

Collaborations

France : Dr. M Fourmigué et Pr. D. Lorcy (Univ. Rennes 1), Dr. E. Levillain (Univ. Angers), Pr. E. Maisonhaute (Sorbonne Univ., UPMC), Pr. F. Banse (Univ. Paris Saclay), Dr. A. Perrier (ChimieParisTech), Pr. H. Gérard (Sorbonne Univ. UPMC), Easy Life Science (société: www.elice.fr)

International : Pr. P. Baeuerle (Univ. Ulm, Germany), Pr. S Huber (Univ. Bochum, Germany), New England Biolabs (société USA : www.neb.com)

 

Keywords

Molecular electrochemistry, organic and organometallic synthesis, supramolecular assemblies, surface functionalization of electrodes, self-assembled monolayers, redox labeling, biomimetic catalysts, halogen bonding, electrochemical sensors, electro-analytic biosensor, nucleic acids in-vitro amplification, redox-active DNA intercalantsg.

 
Elias photo - may 2018
Elias team 05-2017

Group Leader ELIAS

Claire Fave (Associate Scientist CNRS)

Group Members (dec, 2018)

Bernd Schöllhorn (Professor Paris Diderot)
Damien Marchal (Professor Paris Diderot)

Sihem Groni (Chemical Engineer, Paris Diderot)

Hussein Hijazi (PhD student)
Maria Alvarez (PhD student)

 

A selection of recent publications ------------------------------------------------------------------------------------------------------------------------

 

On the decisive role of the sulfur-based anchoring group in the electro-assisted formation of self-assembled monolayers on gold
Dany Capitao, Benoît Limoges, Claire Fave, and Bernd Schöllhorn
Electrochim. Acta, 257 (2017) 165-171. Abstract

Comparative study of non-covalent interactions between cationic N-phenylviologens and halides by electrochemistry and NMR:
the halogen bonding effect

Geordie Creste, Sihem Groni, Claire Fave, Mathieu Branca, and Bernd Schöllhorn
Faraday Discuss., 203 (2017) 301-313. Abstract

Detection of a few DNA copies by real-time electrochemical polymerase chain reaction
Mélanie Moreau, Sébastien Delile, Ashwani Sharma, Claire Fave, Aurélie Perrier, Benoît Limoges, and Damien Marchal
Analyst, 142 (2017) 3432-3440. Abstract

Characterization and subsequent reactivity of an Fe-peroxo porphyrin generated by electrochemical reductive activation of O2
R. Oliveira, W. Zouari, C. Herrero, F. Banse, B. Schöllhorn, C. Fave, and E. Anxolabéhère-Mallart
Anal. Chem., 55 (2016) 12204-12210. Abstract

Self-assembled monolayer formation of a (N5)Fe(II) complex on gold electrodes: electrochemical properties and coordination chemistry on a surface
C. Buron, S. Groni, N. Ségaud, S. Mazerat, D. Dragoe, C. Fave, K. Sénéchal-David, B.Schôllhorn, and F. Banse
Dalton Trans..,45 (2016) 19053-19061. Abstract

Interaction of osmium(II) redox probe with DNA: insights from theory
Ashwani Sharma, Sebastien Delile, Mohamed Jabri, Carlo Adamo, Claire Fave, Damien Marchal, and Aurelie Perrier
Phys. Chem. Chem. Phys., 18 (2016) 30029-30039. Abstract

Electro-assisted deposition of binary self-assembled 1,2-dithiolane monolayers on gold with predictable composition
Dany Capitao, Rihab Sahli, Noureddine Raouafi, Benoit Limoges, Claire Fave, and Bernd Schöllhorn
ChemElectroChem., 3 (2016) 1422-1428. Abstract

Electrochemical activation of a tetrathiafulvalene halogen bond donor in solution
Raquel Oliveira, Sihem Groni, Claire Fave, Mathieu Branca, François Mavré, Dominique Lorcy, Marc Fourmigué, and Bernd Schöllhorn
Phys. Chem. Chem. Phys., 18 (2016) 15867-15873. Abstract

Electrochemical controlling and monitoring of halogen bond formation in solution
Sihem Groni, Tanguy Maby-Raud, Claire Fave, Mathieu Branca, and Bernd Schöllhorn
Chem. Commun., 50 (2014) 14616-14619. Abstract

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